Catalytic water oxidation on derivatized nanoITO

被引：85

作者：

Chen, Zuofeng ^{[1
]}

Concepcion, Javier J. ^{[1
]}

Hull, Jonathan F. ^{[1
]}

Hoertz, Paul G. ^{[1
]}

Meyer, Thomas J. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 30期

关键词：

SINGLE-SITE; RUTHENIUM COMPLEX;

D O I：

10.1039/c0dt00362j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrocatalytic water oxidation occurs on high surface area, nanocrystalline ITO (nanoITO) surface-derivatized by phosphonate-binding of the catalyst [Ru(Mebimpy)-( 4,4 '-((HO)(2)OPCH(2))(2)bpy)(OH(2))](2+) (Mebimpy is 2,6-bis(1-methylbenzimidazol- 2-yl) pyridine; bpy is 2,2 '-bipyridine). With nanoITO, spectral data can be acquired on electrochemically generated intermediates and voltammograms monitored spectrophotometrically.

引用

页码：6950 / 6952

页数：3

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