Transition metal exchanged zeolite layers for selectivity enhancement of metal-oxide semiconductor gas sensors

被引:24
作者
Mann, Dominic P. [1 ]
Pratt, Keith F. E.
Paraskeva, Themis
Parkin, Ivan P.
Williams, David E.
机构
[1] Aeroqual Ltd, Auckland 1003, New Zealand
[2] City Technol Ltd, Portsmouth PO6 1SZ, Hants, England
[3] UCL, Dept Chem, London WC1H 0AJ, England
[4] Univ Auckland, Dept Chem, Auckland 1142, New Zealand
关键词
alkanes; gas sensor; selectivity; zeolite;
D O I
10.1109/JSEN.2007.891956
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
A novel method of improving the selectivity of metal oxide gas sensors has been developed by using catalytically active molecular sieve materials. They have been successfully introduced into a proprietary sensor array. The cracking patterns of linear alkanes over transition metal exchanged zeolite Y have been measured using a zeolite bed/GC/MS experimental set-up within a temperature range of 300 degrees C to 400 degrees C. Studies have been carried out regarding the effects of metal loading, zeolite type, material fabrication techniques, and operating temperature in relation to catalytic activity and selectivity. The composite sensors utilising the novel zeolite materials have been used in a custom built sensor rig that houses three dual electrode sensors and can measure real-time responses of these sensors to an introduced headspace generated from organic liquids.
引用
收藏
页码:551 / 556
页数:6
相关论文
共 12 条
[1]   Decomposition characteristics of chlorinated ethylenes on metal loaded zeolite Y and gamma-Al2O3 [J].
Chintawar, PS ;
Greene, HL .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1997, 13 (02) :81-92
[2]   Synthesis and characterization of [Cr,Al]-ZSM-5 zeolites [J].
Giannetto, G ;
Garcia, L ;
Papa, J ;
Yanez, F ;
Goldwasser, MR ;
Linares, C ;
Moronta, D ;
Mendez, B ;
deNavarro, CU .
ZEOLITES, 1997, 19 (2-3) :169-174
[3]   GAS SENSORS BASED ON OXIDES OF EARLY TRANSITION-METALS [J].
MOSELEY, PT ;
WILLIAMS, DE .
POLYHEDRON, 1989, 8 (13-14) :1615-1618
[4]   MULTIDIMENSIONAL SENSOR FOR GAS-ANALYSIS [J].
MULLER, R ;
LANGE, E .
SENSORS AND ACTUATORS, 1986, 9 (01) :39-48
[5]   Experimental and computational study of the gas-sensor behaviour and surface chemistry of the solid-solution Cr2-xTixO3 (x≤0.5) [J].
Niemeyer, D ;
Williams, DE ;
Smith, P ;
Pratt, KFE ;
Slater, B ;
Catlow, CRA ;
Stoneham, AM .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (03) :667-675
[6]   Preparation and characterization of zeolite-supported molybdenum and cobalt-molybdenum sulfide catalysts [J].
Okamoto, Y .
CATALYSIS TODAY, 1997, 39 (1-2) :45-59
[7]   Surface chemistry and spectroscopy of chromium in inorganic oxides [J].
Weckhuysen, BM ;
Wachs, IE ;
Schoonheydt, RA .
CHEMICAL REVIEWS, 1996, 96 (08) :3327-3349
[8]   Resolving combustible gas mixtures using gas sensitive resistors with arrays of electrodes [J].
Williams, DE ;
Pratt, KFE .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (22) :4497-4504
[9]   THEORY OF SELF-DIAGNOSTIC SENSOR ARRAY DEVICES USING GAS-SENSITIVE RESISTORS [J].
WILLIAMS, DE ;
PRATT, KFE .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1995, 91 (13) :1961-1966
[10]   Microstructure effects on the response of gas-sensitive resistors based on semiconducting oxides [J].
Williams, DE ;
Pratt, KFE .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 70 (1-3) :214-221