A tellurium-triggered domino reaction for the synthesis of a 1-substituted-3-vinyl-1,3-dihydroisobenzofuran

被引：24

作者：

Chao, B ^{[1
]}

Dittmer, DC ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 32期

关键词：

D O I：

10.1016/S0040-4039(00)01047-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Telluride ion reacts with an oxiranemethanol toluenesulfonate in toluene under phase-transfer conditions to give an allylic alkoxide anion that is trapped by addition to an adjacent alpha,beta-unsaturated ester to yield a furan derivative. Use of a non-racemic oxiranemethanol tosylate gives two furan diastereomers in a ratio of 56:44. (C) 2000 Elsevier Science Ltd, All rights reserved.

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页码：6001 / 6004

页数：4

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