Cyclohexadienyl derivatives of (eta(6)-arene)(hydridotris(pyrazolyl) borato) ruthenium(II) compounds

被引:20
作者
Bhambri, S [1 ]
Tocher, DA [1 ]
机构
[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND
关键词
ruthenium; arene; hydrido; tris(pyrazolyl)borato; crystal structure;
D O I
10.1016/0022-328X(95)06011-K
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The addition of nucleophiles X(-) (X = H, D, OH, CN) to the complex cation [Ru(eta(6)-C6H6)(Pz(3)BH)](+) proceeds smoothly to give the neutral cyclohexadienyl compounds [Ru(eta(5)-C(6)H(6)X)(Pz(3)BH)] which are identified by NMR spectroscopy and single crystal X-ray diffraction (for X = CN).
引用
收藏
页码:291 / 293
页数:3
相关论文
共 14 条
[1]   KAPPA(2)-KAPPA(3) ISOMERISM IN RHODIUM(I) TRIS(PYRAZOLYL)BORATE COMPLEXES OF THE TYPE TP(3R,4R,5R)RH(LL) (LL=2 CO, GOD, AND NBD) AND THEIR DYNAMIC BEHAVIOR IN SOLUTION - X-RAY CRYSTAL-STRUCTURE OF TP(ME)RH(NBD) [J].
BUCHER, UE ;
CURRAO, A ;
NESPER, R ;
RUEGGER, H ;
VENANZI, LM ;
YOUNGER, E .
INORGANIC CHEMISTRY, 1995, 34 (01) :66-74
[2]   REACTIONS OF (ETA-6-ARENE)(ETA-6-[2.2]PARACYCLOPHANE)RUTHENIUM(II) COMPLEXES WITH NUCLEOPHILES [J].
ELSEGOOD, MRJ ;
STEED, JW ;
TOCHER, DA .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (11) :1797-1801
[3]  
LEBOZEC H, 1989, ADV ORGANOMET CHEM, V29, P163
[4]   STRUCTURE AND REACTIVITY OF RUTHENIUM HALF-SANDWICH COMPOUNDS - CRYSTAL AND MOLECULAR-STRUCTURE AND ACETONITRILE EXCHANGE KINETICS AND MECHANISM OF RU(ETA-6-C6H6)(CH3CN)3(2+) AND RU(ETA-5-C5H5)(CH3CN)3+ [J].
LUGINBUHL, W ;
ZBINDEN, P ;
PITTET, PA ;
ARMBRUSTER, T ;
BURGI, HB ;
MERBACH, AE ;
LUDI, A .
INORGANIC CHEMISTRY, 1991, 30 (10) :2350-2355
[5]   DOUBLE NUCLEOPHILIC-ADDITION OF CARBON DONORS TO [(BENZENE)(ARENE)RU]2+ CATIONS [J].
NETO, CC ;
SWEIGART, DA .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (23) :1703-1704
[6]   METALLOCENE ANALOGS CONTAINING POLY-1-PYRAZOLYLBORATE OR POLY-1-PYRAZOLYL-METHANE LIGANDS AND FULLY CONJUGATED CARBOCYCLIC PI-ACCEPTOR LIGANDS [J].
OSULLIVA.DJ ;
LALOR, FJ .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 57 (02) :C58-C60
[7]   RUTHENIUM COMPLEXES CONTAINING GROUP VB DONOR LIGANDS .9. CATIONIC ETA-6-ARENE AND ETA-5-CYCLOHEXADIENYL COMPLEXES OF RUTHENIUM CONTAINING NITROGEN AND PHOSPHORUS DONOR LIGANDS [J].
ROBERTSON, DR ;
ROBERTSON, IW ;
STEPHENSON, TA .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 202 (03) :309-318
[8]   SOME ETA-5-CYCLOHEXADIENYL COMPLEXES OF RUTHENIUM [J].
ROBERTSON, DR ;
STEPHENSON, TA .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 142 (02) :C31-C34
[9]  
SHELDRICK GM, 1986, SHELXTL PLUS INTEGRA
[10]   STERICALLY CONTROLLED DOUBLE NUCLEOPHILIC-ADDITION REACTIONS OF (ETA(6)-ARENE)(ETA(6)-[2.2]PARACYCLOPHANE)RUTHENIUM(II) COMPLEXES AND REACTIONS TO FORM HIGHLY FLUXIONAL AGOSTIC CYCLOHEXENYLS [J].
STEED, JW ;
TOCHER, DA .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (21) :3187-3201