Aromatic self-assembled monolayers on hydrogenated silicon

被引：52

作者：

Zharnikov, M ^{[1
]}

Küller, A ^{[1
]}

Shaporenko, A ^{[1
]}

Schmidt, E ^{[1
]}

Eck, W ^{[1
]}

机构：

[1] Univ Heidelberg, D-69120 Heidelberg, Germany

来源：

LANGMUIR | 2003年 / 19卷 / 11期

关键词：

D O I：

10.1021/la020841e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembled monolayers (SAMs) formed from biphenyl-4-ol (BPOH) and p-terphenyl-4-ol (TPOH) on hydrogenated Si substrates were characterized by X-ray photoelectron spectroscopy and angle-resolved near-edge X-ray absorption fine structure spectroscopy. Both aromatic molecules were found to form well-oriented and densely packed films. The packing densities of the aromatic moieties in BPOH/Si and TPOH/Si are quite similar, and the effective film thickness is equal to 10.9 and 15.1 Angstrom, respectively. The average tilt angles of the aromatic backbones in BPOH/Si and TPOH/Si were estimated as 28.7degrees +/- 5degrees and 33degrees +/- 5degrees respectively, which are only slightly larger than the analogous values for the thioaromatic SAMs of the same chain length on noble metal substrates.

引用

收藏

页码：4682 / 4687

页数：6

相关论文

共 74 条

[1] CARBON-1S NEAR-EDGE-ABSORPTION FINE-STRUCTURE IN GRAPHITE [J].

BATSON, PE .

PHYSICAL REVIEW B, 1993, 48 (04) :2608-2610

[2] A FLEXIBLE HIGH-ENERGY TOROIDAL GRATING MONOCHROMATOR AT BESSY [J].

BERNSTORFF, S ;

BRAUN, W ;

MAST, M ;

PEATMAN, W ;

SCHROETER, T .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1989, 60 (07) :2097-2100

[3] Insights into the formation mechanisms of Si-OR monolayers from the thermal reactions of alcohols and aldehydes with Si(111)-H [J].

Boukherroub, R ;

Morin, S ;

Sharpe, P ;

Wayner, DDM ;

Allongue, P .

LANGMUIR, 2000, 16 (19) :7429-7434

[4] New synthetic routes to alkyl monolayers on the Si(111) surface [J].

Boukherroub, R ;

Morin, S ;

Bensebaa, F ;

Wayner, DDM .

LANGMUIR, 1999, 15 (11) :3831-3835

[5] Are single molecular wires conducting? [J].

Bumm, LA ;

Arnold, JJ ;

Cygan, MT ;

Dunbar, TD ;

Burgin, TP ;

Jones, L ;

Allara, DL ;

Tour, JM ;

Weiss, PS .

SCIENCE, 1996, 271 (5256) :1705-1707

[6] STRUCTURES OF SELF-ASSEMBLED MONOLAYERS OF AROMATIC-DERIVATIZED THIOLS ON EVAPORATED GOLD AND SILVER SURFACES - IMPLICATION ON PACKING MECHANISM [J].

CHANG, SC ;

CHAO, I ;

TAO, YT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (15) :6792-6805

[7] STRUCTURAL TRANSITION IN POLYPHENYLS .3. CRYSTAL-STRUCTURE OF BIPHENYL AT 110 K [J].

CHARBONNEAU, GP ;

DELUGEARD, Y .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (MAY15) :1420-1423

[8] Distance dependence of the electron-transfer rate across covalently bonded monolayers on silicon [J].

Cheng, J ;

Robinson, DB ;

Cicero, RL ;

Eberspacher, T ;

Barrelet, CJ ;

Chidsey, CED .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (44) :10900-10904

[9] DIRECT FUNCTIONALIZATION OF SILICON VIA THE SELF-ASSEMBLY OF ALCOHOLS [J].

CLELAND, G ;

HORROCKS, BR ;

HOULTON, A .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1995, 91 (21) :4001-4003

[10]

COLONGE J, 1967, B SOC CHIM FR, P4370

← 1 2 3 4 5 6 7 8 →