Amido→azaallyl transformation in sodium amide complexes of (S)-α-(methylbenzyl)benzylamine

被引：14

作者：

Andrews, PC ^{[1
]}

Duggan, PJ

Fallon, GD

McCarthy, TD

Peatt, AC

机构：

[1] Monash Univ, Dept Chem, Melbourne, Vic 3800, Australia

[2] Biomol Res Inst, Melbourne, Vic 3169, Australia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 15期

关键词：

D O I：

10.1039/b003826l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of (S)-{[(Ph(Me)CH)(PhCH2)]NNa}(n) with pmdeta (N,N,N',N',N "-pentamethyldiethylenetriamine) produces red/green dichroic crystals of the azaallylic complexes {[Ph(Me)CNC(H)Ph]Na . pmdeta}, 3, and {[(PhCH)(2)N]Na . pmdeta}, 2; by X-ray diffraction 3 is found to be monomeric and structurally similar to the previously characterised 2.

引用

页码：2505 / 2507

页数：3

共 17 条

[1] Solid state structures of the chiral lithium amide complexes (S)-[(Ph(Me)CH)(PhCH2)NLi•thf]2 and (R)-[(Ph(Me)CH)(PhCH2)NLi•pmdta]
Andrews, PC
Duggan, PJ
Fallon, GD
McCarthy, TD
Peatt, AC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (12): : 1937 - 1940
[2] X-RAY CRYSTALLOGRAPHIC STUDIES AND DYNAMIC H-1-NMR SPECTROSCOPIC STUDIES OF THE NOVEL SODIUM AZA-ALLYL MONOMER ([PHC(H)NC(H)PH]NA.PMDETA) - A DISCRETE CONTACT ION-PAIR STRUCTURE HELD TOGETHER BY A SHORT N-NA BOND, AND SHOWING CLOSE (ORTHO-PH)C-H ... NA CONTACTS IN BOTH SOLID-STATE AND SOLUTION
ANDREWS, PC
MULVEY, RE
CLEGG, W
REED, D
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 386 (03) : 287 - 297
[3] EVIDENCE FOR EXTREME ACTIVATION OF C-H BONDS IN [(PHCH2)2NNA]N - RESULTANT C-H BOND-CLEAVAGE TO GIVE ([PHC(H)NC(H)PH]NA.PMDETA)N
ANDREWS, PC
ARMSTRONG, DR
MULVEY, RE
REED, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (15) : 5235 - 5236
[4] SYNTHETIC, STRUCTURAL, MECHANISTIC, AND THEORETICAL MO STUDIES OF THE ALKALI-METAL CHEMISTRY OF DIBENZYLAMINE AND ITS TRANSFORMATION TO 1,3-DIPHENYL-2-AZAALLYL DERIVATIVES
ANDREWS, PC
ARMSTRONG, DR
BAKER, DR
MULVEY, RE
CLEGG, W
HORSBURGH, L
ONEIL, PA
REED, D
[J]. ORGANOMETALLICS, 1995, 14 (01) : 427 - 439
[5] Thermal cyclodimerization of aliphatic secondary C,N-dilithioallylamine derivatives
Barluenga, J
Canteli, RM
Florez, J
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (11) : 3753 - 3757
[6] Formation of α-dialkylamino alkyllithium intermediates in the reaction of N,N-dialkylamides with PhMe2SiLi followed by a second lithium reagent, and their alkylation, fragmentation, cyclisation and rearrangement by proton transfer
Fleming, I
Mack, SR
Clark, BP
[J]. CHEMICAL COMMUNICATIONS, 1998, (06) : 715 - 716
[7] Aluminium amides derived from metallation of N,N'-di-tert-butylethylenediamine
Gardiner, MG
Lawrence, SM
Raston, CL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (22): : 4163 - 4169
[8] PYROLYSIS OF UNSOLVATED ALKYLLITHIUM COMPOUNDS
GLAZE, WH
LIN, J
FELTON, EG
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (08) : 2643 - &
[9] TRANSITION STRUCTURES FOR ADDITIONS OF LIH AND MELI TO ETHYLENE AND ACETYLENE
HOUK, KN
RONDAN, NG
SCHLEYER, PV
KAUFMANN, E
CLARK, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (09) : 2821 - 2823
[10] Junge K, 1999, Z ANORG ALLG CHEM, V625, P1532, DOI 10.1002/(SICI)1521-3749(199909)625:9<1532::AID-ZAAC1532>3.0.CO

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