[n-Bu4N][Δ-TRISPHAT] salt, an efficient NMR chiral shift reagent for neutral planar chiral tricarbonylchromium complexes

被引:53
作者
Ratni, H [1 ]
Jodry, JJ [1 ]
Lacour, J [1 ]
Kündig, EP [1 ]
机构
[1] Univ Geneva, Dept Chim Organ, CH-1211 Geneva 4, Switzerland
关键词
D O I
10.1021/om000437f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The determination of the enantiomeric purity of planar chiral Cr(CO)(3) complexes of substituted benzaldehydes and nitrones has been conveniently carried out by H-1 NMR analysis using a TRISPHAT salt as a diamagnetic chiral shift reagent.
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页码:3997 / 3999
页数:3
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