Platinum determination by instrumental neutron activation analysis with special reference to the spectral interference of Sc-47 on the platinum indicator nuclide Au-199

被引：18

作者：

Alfassi, ZB ^{[1
]}

Probst, TU

Rietz, B

机构：

[1] Ben Gurion Univ Negev, Dept Nucl Engn, IL-84102 Beer Sheva, Israel

[2] Tech Univ Munchen, Inst Radiochem, D-85747 Garching, Germany

[3] Riso Natl Lab, Isotope Div, DK-4000 Roskilde, Denmark

来源：

ANALYTICA CHIMICA ACTA | 1998年 / 360卷 / 1-3期

关键词：

platinum determination; instrumental neutron activation analysis (INAA); calculation of the interference of Sc-47 to Au-199; environmental samples;

D O I：

10.1016/S0003-2670(97)00711-3

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A method of instrumental neutron activation analysis (INAA) is developed for the determination of platinum by the Au-199 daughter of Pt-199 in the presence of the spectral interference from the Sc-47 daughter of Ca-47. The contributions of the Pt and Ca signals to the integral 157-161 keV peak were separated by calculating the number of disintegrations due to the Sc-47 from the signal of her parent Ca-47 at 1297.1 keV gamma-ray. The method was used to calculate the trace concentrations of Pt in air samples, collected on filters, (C) 1998 Elsevier Science B.V.

引用

页码：243 / 252

页数：10

共 33 条

[1] DETERMINATION OF NOBLE-METALS IN GEOLOGICAL MATERIALS BY RADIOCHEMICAL NEUTRON-ACTIVATION ANALYSIS [J].

AHMAD, I ;

AHMAD, S ;

MORRIS, DFC .

ANALYST, 1977, 102 (1210) :17-24

[2] DETERMINATION OF ALUMINUM BY INSTRUMENTAL NEUTRON-ACTIVATION ANALYSIS IN BIOLOGICAL SAMPLES WITH SPECIAL REFERENCE TO NBS-SRM-1577 BOVINE LIVER [J].

ALFASSI, ZB ;

RIETZ, B .

ANALYST, 1994, 119 (11) :2407-2410

[3]

ALFASSI ZB, 1990, ACTIVATION ANAL, P3

[4] A contribution to the ecology and enology of platinum [J].

Alt, F ;

Eschnauer, HR ;

Mergler, B ;

Messerschmidt, J ;

Tolg, G .

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1997, 357 (08) :1013-1019

[5] PLATINUM TRACES IN AIRBORNE PARTICULATE MATTER - DETERMINATION OF WHOLE CONTENT, PARTICLE-SIZE DISTRIBUTION AND SOLUBLE PLATINUM [J].

ALT, F ;

BAMBAUER, A ;

HOPPSTOCK, K ;

MERGLER, B ;

TOLG, G .

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1993, 346 (6-9) :693-696

[6]

[Anonymous], 1972, RECENT ADV ANAL CHEM

[7] ELIMINATION OF REAGENT BLANK PROBLEMS IN THE FIRE-ASSAY PRE-CONCENTRATION OF THE PLATINUM GROUP ELEMENTS AND GOLD WITH A NICKEL SULFIDE BEAD OF LESS THAN ONE GRAM MASS [J].

ASIF, M ;

PARRY, SJ .

ANALYST, 1989, 114 (09) :1057-1059

[8]

BEAMISH FE, 1972, MINER SCI ENG, V4, P3

[9]

BRUEGMANN GE, 1990, J GEOCHEM EXPLOR, V37, P25

[10]

Friedlander G., 1981, Nuclear and radiochemistry

← 1 2 3 4 →