Diisopropoxyaluminium trifluoroacetate/4-nitrobenzaldehyde - A new Oppenauer oxidation system for accelerated oxidation of secondary alcohols to the corresponding ketones

被引：19

作者：

Akamanchi, KG

Chaudhari, BA

机构：

[1] Pharmaceut. and Fine Chem. Division, Department of Chemical Technology, University of Mumbai, Matunga

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 39期

关键词：

D O I：

10.1016/S0040-4039(97)01623-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A practical, efficient and accelerated oxidation of secondary alcohols to the corresponding ketones has been achieved at rt in high yields by a modified Oppenauer oxidation system using diisopropoxyaluminium trifluoroacetate as catalyst and 4-nitrobenzaldehyde as a hydride acceptor. (C) 1997 Elsevier Science Ltd.

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页码：6925 / 6928

页数：4

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