Synthesis of nano-structured titanium carbide by Mg-thermal reduction

被引:60
作者
Lee, DW [1 ]
Kim, BK [1 ]
机构
[1] KIMM, Nano PM Grp, Dept Mat Technol, Kyungnam 641010, South Korea
关键词
carbides; nano-crystalline materials; metal-thermal reduction;
D O I
10.1016/S1359-6462(03)00130-1
中图分类号
TB3 [工程材料学];
学科分类号
0805 [材料科学与工程]; 080502 [材料学];
摘要
Nano-structured titanium carbides were synthesized by liquid-magnesium reduction of vaporized TiCl4 + CCl4 solution. Fine TiC particles were produced by the reaction of released Ti and C atoms, and vacuum was used to remove the residual phases of MgCl2 and excess Mg. Characterization of products was performed with various reaction parameters. (C) 2003 Acta Materialia Inc. Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1513 / 1518
页数:6
相关论文
共 7 条
[1]
Production of titanium carbide, nitride and carbonitride by metallothermic reduction of halogenides [J].
Aleksandrovskii, SV ;
Sizyakov, VM ;
Ratner, AK ;
Lee, DW .
JOURNAL OF MATERIALS PROCESSING & MANUFACTURING SCIENCE, 2001, 9 (04) :303-309
[2]
Titanium carbide based composites for high temperature applications [J].
Durlu, N .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1999, 19 (13-14) :2415-2419
[3]
T1(C,N) CERMETS - METALLURGY AND PROPERTIES [J].
ETTMAYER, P ;
KOLASKA, H ;
LENGAUER, W ;
DREYER, K .
INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 1995, 13 (06) :343-351
[4]
An experimental investigation of possible B2-ordering in the Al-Cr system [J].
Helander, T ;
Tolochko, O .
JOURNAL OF PHASE EQUILIBRIA, 1999, 20 (01) :57-60
[5]
Reaction synthesis mechanism in dynamically densified Ti+C powder compacts [J].
Lee, JH ;
Thadhani, NN .
SCRIPTA MATERIALIA, 1997, 37 (12) :1979-1985
[6]
Studies on the carbothermal preparation of titanium carbide from different gel precursors [J].
Preiss, H ;
Berger, LM ;
Schultze, D .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1999, 19 (02) :195-206
[7]
SAMSONOV GV, 1974, REFRACTORY CARBIDES, P341