Direct observation of enantiomer discrimination of epoxides by chiral salen complexes using ENDOR

被引:27
作者
Fallis, IA [1 ]
Murphy, DM [1 ]
Willock, DJ [1 ]
Tucker, RJ [1 ]
Farley, RD [1 ]
Jenkins, R [1 ]
Strevens, RR [1 ]
机构
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3TB, S Glam, Wales
关键词
D O I
10.1021/ja045491s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
[No abstract available]
引用
收藏
页码:15660 / 15661
页数:2
相关论文
共 16 条
[2]   Stereoselective recognition of an aziridine with a Co(III) complex: A potential transition-state analogue for catalytic epoxidation [J].
Bobb, R ;
Alhakimi, G ;
Studnicki, L ;
Lough, A ;
Chin, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (17) :4544-4545
[3]   Spectroscopic investigations of bis(sulfoximine) copper(II) complexes and their relevance in asymmetric catalysis [J].
Bolm, C ;
Martin, M ;
Gescheidt, G ;
Palivan, C ;
Neshchadin, D ;
Bertagnolli, H ;
Feth, M ;
Schweiger, A ;
Mitrikas, G ;
Harmer, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (20) :6222-6227
[4]   On the mechanism of asymmetric nucleophilic ring-opening of epoxides catalyzed by (salen)Cr-III complexes [J].
Hansen, KB ;
Leighton, JL ;
Jacobsen, EN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (44) :10924-10925
[5]   GENERAL-THEORY OF POLYCRYSTALLINE ENDOR PATTERNS - G AND HYPERFINE TENSORS OF ARBITRARY SYMMETRY AND RELATIVE ORIENTATION [J].
HOFFMAN, BM ;
MARTINSEN, J ;
VENTERS, RA .
JOURNAL OF MAGNETIC RESONANCE, 1984, 59 (01) :110-123
[6]   Electron-nuclear double resonance spectroscopy (and electron spin-echo envelope modulation spectroscopy) in bioinorganic chemistry [J].
Hoffman, BM .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2003, 100 (07) :3575-3578
[7]   ANGLE-SELECTED ENDOR SPECTROSCOPY .1. THEORETICAL INTERPRETATION OF ENDOR SHIFTS FROM RANDOMLY ORIENTATED TRANSITION-METAL COMPLEXES [J].
HURST, GC ;
HENDERSON, TA ;
KREILICK, RW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (25) :7294-7299
[8]  
MASON SF, 1980, MOL OPTICAL ACTIVITY
[9]   Conformational changes of an oxovanadium complex probed by ENDOR spectroscopy and DFT calculations [J].
Murphy, DM ;
Fallis, IA ;
Farley, RD ;
Tucker, RJ ;
Avery, KL ;
Willock, DJ .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2002, 4 (20) :4937-4943
[10]   Mechanistic investigation leads to a synthetic improvement in the hydrolytic kinetic resolution of terminal epoxides [J].
Nielsen, LPC ;
Stevenson, CP ;
Blackmond, DG ;
Jacobsen, EN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (05) :1360-1362