Effective interactions between electric double layers

被引:414
作者
Hansen, JP
Löwen, H
机构
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
[2] Univ Dusseldorf, Inst Theoret Phys 2, D-40225 Dusseldorf, Germany
关键词
density functional; charged colloids; correlations; Poisson-Boltzmann theory; Debye screening;
D O I
10.1146/annurev.physchem.51.1.209
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This review summarizes and assesses recent theoretical and experimental advances, with special emphasis on the effective interaction between charge-stabilized colloids, in the hulk or in confined geometries, and on the ambiguities of defining an effective charge of the colloidal particles. Some consideration is given to the often neglected discrete solvent effects.
引用
收藏
页码:209 / 242
页数:34
相关论文
共 195 条
[131]   Counterion condensation theory constructed from different models [J].
Manning, GS .
PHYSICA A, 1996, 231 (1-3) :236-253
[132]   CALCULATION OF THERMODYNAMIC PROPERTIES OF POLYELECTROLYTES [J].
MARCUS, RA .
JOURNAL OF CHEMICAL PHYSICS, 1955, 23 (06) :1057-1068
[133]   PHASE-DIAGRAM OF COLLOIDAL DISPERSIONS OF ANISOTROPIC CHARGED-PARTICLES - EQUILIBRIUM PROPERTIES, STRUCTURE, AND RHEOLOGY OF LAPONITE SUSPENSIONS [J].
MOURCHID, A ;
DELVILLE, A ;
LAMBARD, J ;
LECOLIER, E ;
LEVITZ, P .
LANGMUIR, 1995, 11 (06) :1942-1950
[134]  
NAGY M, 1989, POLYM COMMUN, V30, P133
[135]   Field theory for charged fluids and colloids [J].
Netz, RR ;
Orland, H .
EUROPHYSICS LETTERS, 1999, 45 (06) :726-732
[136]   Wall-mediated forces between like-charged bodies in an electrolyte [J].
Neu, JC .
PHYSICAL REVIEW LETTERS, 1999, 82 (05) :1072-1074
[137]   ELECTROSTATIC POTENTIAL BETWEEN SUFRACES BEARING IONIZABLE GROUPS IN IONIC EQUILIBRIUM WITH PHYSIOLOGIC SALINE SOLUTION [J].
NINHAM, BW ;
PARSEGIAN, VA .
JOURNAL OF THEORETICAL BIOLOGY, 1971, 31 (03) :405-+
[138]   INTERACTION BETWEEN PARALLEL RODLIKE MACROIONS [J].
OOSAWA, F .
BIOPOLYMERS, 1968, 6 (11) :1633-&
[139]   Solving the Poisson-Boltzmann equation to obtain interaction energies between confined, like-charged cylinders [J].
Ospeck, M ;
Fraden, S .
JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (20) :9166-9171
[140]   Forces between like-charged plates in electrolyte solution: Ion-solvent packing versus electrostatic effects [J].
Otto, F ;
Patey, GN .
PHYSICAL REVIEW E, 1999, 60 (04) :4416-4422