Molecular level dispersed Pd clusters in the carbon walls of ordered mesoporous carbon as a highly selective alcohol oxidation catalyst

被引：112

作者：

Lu, An-Hui ^{[1
]}

Li, Wen-Cui ^{[1
]}

Hou, Zhenshan ^{[1
]}

Schueth, Ferdi ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 10期

关键词：

D O I：

10.1039/b613834a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ordered mesoporous carbon containing molecular-level dispersed Pd clusters in the carbon walls can be synthesized by the nanocasting pathway, which shows high selectivity for the oxidation of alcohols to aldehydes.

引用

页码：1038 / 1040

页数：3

共 21 条

[1] Highly selective oxidation of allylic alcohols catalysed by monodispersed 8-shell Pd nanoclusters in the presence of molecular oxygen [J].

Choi, KM ;

Akita, T ;

Mizugaki, T ;

Ebitani, K ;

Kaneda, K .

NEW JOURNAL OF CHEMISTRY, 2003, 27 (02) :324-328

[2] Platinum nanoclusters studded in the microporous nanowalls of ordered mesoporous carbon [J].

Choi, WC ;

Woo, SI ;

Jeon, MK ;

Sohn, JM ;

Kim, MR ;

Jeon, HJ .

ADVANCED MATERIALS, 2005, 17 (04) :446-+

[3] From microporous to mesoporous molecular sieve materials and their use in catalysis [J].

Corma, A .

CHEMICAL REVIEWS, 1997, 97 (06) :2373-2419

[4] Solvent-free oxidation of primary alcohols to aldehydes using Au-Pd/TiO2 catalysts [J].

Enache, DI ;

Edwards, JK ;

Landon, P ;

Solsona-Espriu, B ;

Carley, AF ;

Herzing, AA ;

Watanabe, M ;

Kiely, CJ ;

Knight, DW ;

Hutchings, GJ .

SCIENCE, 2006, 311 (5759) :362-365

[5] Encapsulation of metal particles within the wall structure of mesoporous carbons [J].

Holmes, SM ;

Foran, P ;

Roberts, EPL ;

Newton, JM .

CHEMICAL COMMUNICATIONS, 2005, (14) :1912-1913

[6] Biphasic aerobic oxidation of alcohols catalyzed by poly(ethylene glycol)-stabilized palladium nanoparticles in supercritical carbon dioxide [J].

Hou, Z ;

Theyssen, N ;

Brinkmann, A ;

Leitner, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (09) :1346-1349

[7] Novel mesoporous materials with a uniform distribution of organic groups and inorganic oxide in their frameworks [J].

Inagaki, S ;

Guan, S ;

Fukushima, Y ;

Ohsuna, T ;

Terasaki, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) :9611-9614

[8] Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure [J].

Jun, S ;

Joo, SH ;

Ryoo, R ;

Kruk, M ;

Jaroniec, M ;

Liu, Z ;

Ohsuna, T ;

Terasaki, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) :10712-10713

[9] Comparative study of silylation methods to improve the stability of silicate MCM-41 in aqueous solutions [J].

Kisler, JM ;

Gee, ML ;

Stevens, GW ;

O'Connor, AJ .

CHEMISTRY OF MATERIALS, 2003, 15 (03) :619-624

[10] Fabrication of magnetically separable mesostructured silica with an open pore system [J].

Lu, AH ;

Li, WC ;

Kiefer, A ;

Schmidt, W ;

Bill, E ;

Fink, G ;

Schüth, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (28) :8616-8617

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