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Activity and stability enhancement of Ni-MCM-41 catalysts by Rh incorporation for hydrogen from dry reforming of methane

被引：137
作者：
Arbag, Huseyin [1 ]
Yasyerli, Sena [1 ]
Yasyerli, Nail [1 ]
Dogu, Gulsen [1 ]
机构：
[1] Gazi Univ, Dept Chem Engn, TR-06520 Ankara, Turkey
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2010年 / 35卷 / 06期
关键词：
Hydrogen; Dry reforming; Rh-Ni-MCM-41; Ni-MCM-41; Catalyst stability; CARBON-DIOXIDE; SYNTHESIS GAS; COKE FORMATION; CO2; SUPPORT; NI; ZRO2; CH4; PD;
D O I：
10.1016/j.ijhydene.2009.12.109
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ni incorporated and Ni-Rh incorporated bimetallic MCM-41 like mesoporous catalysts, which were synthesized following a one-pot hydrothermal procedure, showed very high activity in dry reforming of methane. Among the Ni incorporated catalysts, Ni-MCM-41-V, with a Ni/Si ratio of 0.19, showed the best catalytic performance. Rh incorporation into this catalyst by the one-pot procedure improved both activity and time on stream stability of the catalyst. However, Rh incorporation by impregnation caused instabilities due to coke formation, after about 11 h of reaction time. Occurrence of reverse water gas shift reaction caused higher CO selectivity than H-2 selectivity, with the Ni incorporated catalysts. Rh incorporation into these catalysts decreased the relative significance of reverse water gas shift reaction, with respect to dry reforming reaction. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
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页码：2296 / 2304
页数：9
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