Abatement of gas-phase p-xylene via dielectric barrier discharges

被引:96
作者
Lee, HM [1 ]
Chang, MB [1 ]
机构
[1] Natl Cent Univ, Grad Inst Environm Engn, Chungli 320, Taiwan
关键词
dielectric barrier discharges; para-xylene removal; air pollution; control technology; energy efficiency; nonthermal plasmas; ATMOSPHERIC PHOTOOXIDATION; OZONE SYNTHESIS; REACTOR; DESTRUCTION; MECHANISM; REMOVAL; TOLUENE;
D O I
10.1023/A:1023239122885
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The effectiveness of applying dielectric barrier discharges (DBDs) to remove p-xylene from gas streams was experimentally investigated in this study. Parameters investigated include applied voltage, gas flow rate, gas temperature and gas composition. Experimental results indicate that as high as 100% p-xylene removal efficiency is achieved for the gas stream containing low p-xylene concentration of 26 ppmv. Removal efficiency of p-xylene achieved with DBDs increases with increasing applied voltage. However, energy consumption is also increased with increasing applied voltage. The best energy efficiency of 7.1 g/k Wh is achieved for the gas streams containing 500 ppmv p-xylene, 5% O-2, 1.6% H2O(g), and balanced N-2 at the applied voltage of 18 kV. Product analysis indicates that around 70 or 95% of the carbons in p-xylene molecules are transformed into carbon dioxide for the gas streams without or with water vapor, respectively.
引用
收藏
页码:541 / 558
页数:18
相关论文
共 25 条
[1]   Oxidation of styrene in a silent discharge plasma [J].
Anderson, GK ;
Snyder, H ;
Coogan, J .
PLASMA CHEMISTRY AND PLASMA PROCESSING, 1999, 19 (01) :131-151
[2]   Mechanism of atmospheric photooxidation of aromatics: A theoretical study [J].
Andino, JM ;
Smith, JN ;
Flagan, RC ;
Goddard, WA ;
Seinfeld, JH .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (26) :10967-10980
[3]  
[Anonymous], CHEM REV
[4]  
[Anonymous], 1986, ENV POL SUS DEV
[5]   Energy characteristics of the process of air scrubbing from hydrocarbon contaminants in a barrier-discharge reactor [J].
Bugaev, SP ;
Kuvshinov, VA ;
Sochugov, NS ;
Khryapov, PA .
PLASMA CHEMISTRY AND PLASMA PROCESSING, 1996, 16 (04) :669-677
[6]  
CHANDENIER J, 1995, B SOC PATHOL EXOT, V88, P18
[7]   Destruction and removal of toluene and MEK from gas streams with silent discharge plasmas [J].
Chang, MB ;
Chang, CC .
AICHE JOURNAL, 1997, 43 (05) :1325-1330
[8]   Experimental study on ozone synthesis via dielectric barrier discharges [J].
Chang, MB ;
Wu, SJ .
OZONE-SCIENCE & ENGINEERING, 1997, 19 (03) :241-254
[9]  
DORAI R, 2000, THESIS U ILLINOIS
[10]   OZONE SYNTHESIS FROM OXYGEN IN DIELECTRIC BARRIER DISCHARGES [J].
ELIASSON, B ;
HIRTH, M ;
KOGELSCHATZ, U .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1987, 20 (11) :1421-1437