Hydrogen bonding of water with aromatic hydrocarbons high temperature and pressure

被引：26

作者：

Furutaka, S ^{[1
]}

Ikawa, S ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan

来源：

JOURNAL OF CHEMICAL PHYSICS | 1998年 / 108卷 / 13期

关键词：

D O I：

10.1063/1.475953

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Infrared spectra of HDO dissolved in benzene, toluene, ethylbenzene, o-xylene, m-xylene, and mesitylene at 373-473 K and 100 bar have been measured. It is found that the peak positions of the OH bands assigned to monomeric HDO shift to lower wave numbers as ionization energies of the aromatic compounds decrease. It is concluded that the interaction of water and aromatic compounds in the high temperature-pressure mixtures can be described as pi-hydrogen bonding as for that in their complexes observed in the low temperature matrices and jet-cooled clusters. (C) 1998 American Institute of Physics.

引用

页码：5159 / 5160

页数：2

共 13 条

[1] HYDROLYSIS AND OXIDATION IN SUPERCRITICAL WATER [J].

BOOCK, LT ;

LAMARCA, C ;

KLEIN, MT .

ENDEAVOUR, 1993, 17 (04) :180-185

[2] SOLUBILITY OF HYDROCARBONS IN WATER NEAR CRITICAL SOLUTION TEMPERATURES [J].

CONNOLLY, JF .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1966, 11 (01) :13-&

[3] THE STATIC DIELECTRIC-CONSTANT OF THE WATER-BENZENE MIXTURE SYSTEM TO 400-DEGREES-C AND 2800-BAR [J].

DEUL, R ;

FRANCK, EU .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1991, 95 (08) :847-853

[4] A MATRIX-ISOLATION STUDY OF THE INTERACTION BETWEEN WATER AND THE AROMATIC PI-ELECTRON SYSTEM [J].

ENGDAHL, A ;

NELANDER, B .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (09) :2253-2258

[5] PHYSICOCHEMICAL PROPERTIES OF SUPERCRITICAL SOLVENTS [J].

FRANCK, EU .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1984, 88 (09) :820-825

[6] Infrared study of water in benzene at high temperatures and pressure [J].

Furutaka, S ;

Ikawa, S .

JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (04) :1347-1351

[7] Infrared spectrum of a molecular ice cube: The S-4 and D-2d water octamers in benzene-(water)(8) [J].

Gruenloh, CJ ;

Carney, JR ;

Arrington, CA ;

Zwier, TS ;

Fredericks, SY ;

Jordan, KD .

SCIENCE, 1997, 276 (5319) :1678-1681

[8] OXIDATION AND HYDROTHERMOLYSIS OF HYDROCARBONS IN SUPERCRITICAL WATER AT HIGH-PRESSURES [J].

HIRTH, T ;

FRANCK, EU .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1993, 97 (09) :1091-1098

[9] SONOLYTIC HYDROLYSIS OF P-NITROPHENYL ACETATE - THE ROLE OF SUPERCRITICAL WATER [J].

HUA, I ;

HOCHEMER, RH ;

HOFFMANN, MR .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (08) :2335-2342

[10]

LIAS SG, 1988, J PHYS CHEM REF DATA, V17, P1

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