A breakthrough in the safety of lithium secondary batteries by coating the cathode material with AIPO4 nanoparticles

被引：345

作者：

Cho, J ^{[1
]}

Kim, YW

Kim, B

Lee, JG

Park, B

机构：

[1] Kumoh Natl Inst Technol, Dept Appl Chem, Gumi 730701, South Korea

[2] Seoul Natl Univ, Sch Mat Sci & Engn, Res Ctr Energy Convers & Storage, Seoul 151744, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 14期

关键词：

coatings; electrochemistry; electrodes; lithium; safety;

D O I：

10.1002/anie.200250452

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hard cell! There have been numerous reports highlighting the questionable safety of lithium secondary batteries, an example of which is shown here, where exothermic reactions of LiCoO2 electrodes have considerable fire and explosion potential. The coating of such electrodes with a layer of AlPO4 nanoparticles is shown to reduce these risks significantly, even where a short circuit of the cell was observed.

引用

页码：1618 / 1621

页数：4

共 24 条

[1] Organization of 'nanocrystal molecules' using DNA
Alivisatos, AP
Johnsson, KP
Peng, XG
Wilson, TE
Loweth, CJ
Bruchez, MP
Schultz, PG
[J]. NATURE, 1996, 382 (6592) : 609 - 611
[2] ''Coulomb staircase'' at room temperature in a self-assembled molecular nanostructure
Andres, RP
Bein, T
Dorogi, M
Feng, S
Henderson, JI
Kubiak, CP
Mahoney, W
Osifchin, RG
Reifenberger, R
[J]. SCIENCE, 1996, 272 (5266) : 1323 - 1325
[3] Bard A. J., 2001, ELECTROCHEMICAL METH, P544
[4] On safety of lithium-ion cells
Biensan, P
Simon, B
Pérès, JP
de Guibert, A
Broussely, M
Bodet, JM
Perton, F
[J]. JOURNAL OF POWER SOURCES, 1999, 81 : 906 - 912
[5] Cassagneau T, 2002, ADV MATER, V14, P732, DOI 10.1002/1521-4095(20020517)14:10<732::AID-ADMA732>3.0.CO
[6] 2-P
[7] Cho J, 2001, ANGEW CHEM INT EDIT, V40, P3367, DOI 10.1002/1521-3773(20010917)40:18<3367::AID-ANIE3367>3.0.CO
[8] 2-A
[9] Novel LiCoO2 cathode material with Al2O3 coating for a Li ion cell
Cho, J
Kim, YJ
Park, B
[J]. CHEMISTRY OF MATERIALS, 2000, 12 (12) : 3788 - 3791
[10] *JAP BATT ASS, 1997, GUID SAF EV SEC LITH

← 1 2 3 →