Synthesis and Properties of Layered-Structured Mn5O8 Nanorods

被引：101

作者：

Gao, Tao ^{[1
,2
]}

Norby, Poul ^{[3
]}

Krumeich, Frank ^{[4
]}

Okamoto, Hiroshi ^{[1
,2
]}

Nesper, Reinhard ^{[4
]}

Fjellvag, Helmer ^{[1
,2
]}

机构：

[1] Univ Oslo, Ctr Mat Sci & Nanotechnol, N-0315 Oslo, Norway

[2] Univ Oslo, Dept Chem, N-0315 Oslo, Norway

[3] Tech Univ Denmark, Riso Natl Lab Sustainable Energy, Mat Res Div, DK-4000 Roskilde, Denmark

[4] ETH, Inorgan Chem Lab, CH-8093 Zurich, Switzerland

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2010年 / 114卷 / 02期

关键词：

SYSTEM MN-O; MANGANESE OXIDES; RAMAN-SPECTROSCOPY; LITHIUM BATTERIES; MN3O4; STABILITY; SIZE; MICROSTRUCTURES; TRANSITION; OXIDATION;

D O I：

10.1021/jp9097606

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mn5O8 nanorods were prepared by a topotactic conversion of gamma-MnOOH nanorod precursors in nitrogen at 400 degrees C. The as-prepared Mn5O8 nanorods crystallized in a monoclinic structure (space group C2/m) with unit cell dimensions a = 10.3784(2) angstrom, b = 5.7337(7) angstrom, c = 4.8668(6) angstrom, and beta = 109.491(6)degrees, having a compositional formula Mn22+Mn34+O8. The structure allowed 18 Raman-active modes (10 A(g) + 8 B-g); 10 of these contributions were observed at 262, 300, 391, 429, 475, 533, 576, 615, 647, and 789 cm(-1). An intensive A(g) mode at 647 cm(-1) was identified, representing a clear signature for probing the Mn5O8 materials via Raman scattering. X-ray photoelectron spectroscopy studies revealed the distinctive spectral features of the Mn5O8 due to the coexistence of divalent and tetravalent Mn ions. Magnetic measurements confirmed further that Mn5O8 was a mixed valence oxide with an antiferromagnetic transition at about 133 K. The decreased Neel temperature of the Mn5O8 nanorods Suggested the possible presence of the finite size effect, which accounted also for the red-shift of the corresponding Raman bands in comparison with those of the bulk counterparts.

引用

页码：922 / 928

页数：7

共 45 条

[1] A STUDY OF A NUMBER OF MIXED TRANSITION-METAL OXIDE SPINELS USING X-RAY PHOTOELECTRON-SPECTROSCOPY [J].

ALLEN, GC ;

HARRIS, SJ ;

JUTSON, JA ;

DYKE, JM .

APPLIED SURFACE SCIENCE, 1989, 37 (01) :111-134

[2] STRUCTURE OF CALCIUM MANGANESE OXIDE CA2MN3O8 [J].

ANSELL, GB ;

MODRICK, MA ;

LONGO, JM ;

POEPPELMEIER, KR ;

HOROWITZ, HS .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (JUN) :1795-1797

[3] Mn3O4 and γ-MnOOH powders, preparation, phase composition and XPS characterisation [J].

Ardizzone, S ;

Bianchi, CL ;

Tirelli, D .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1998, 134 (03) :305-312

[4]

Auerbach S. M., 2004, HDB LAYERED MAT, P475

[5] Thermal stability and structural transition of metastable Mn5O8:: in situ micro-Raman study [J].

Azzoni, CB ;

Mozzati, MC ;

Galinetto, P ;

Paleari, A ;

Massarotti, V ;

Capsoni, D ;

Bini, M .

SOLID STATE COMMUNICATIONS, 1999, 112 (07) :375-378

[6]

Bean C., 1959, J. Appl. Phys, V30, pS120, DOI [DOI 10.1063/1.2185850, 10.1063/1.2185850]

[7]

BRICKER O, 1965, AM MINERAL, V50, P1296

[8] Layered manganese oxide intergrowth electrodes for rechargeable lithium batteries.: 1.: Substitution with Co or Ni [J].

Dollé, M ;

Patoux, S ;

Doeff, MM .

CHEMISTRY OF MATERIALS, 2005, 17 (05) :1036-1043

[9] Synthesis of MnOOH nanorods by cluster growth route from [Mn12O12(RCOO)16(H2O)n] (R = CH3, C2H5).: Rational conversion of MnOOH into Mn3O4 or MnO2 nanorods [J].

Folch, B ;

Larionova, J ;

Guari, Y ;

Guérin, C ;

Reibel, C .

JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (07) :2368-2375

[10] Low-temperature oxidation of Mn3O4 hausmannite [J].

Fritsch, S ;

Sarrias, J ;

Rousset, A ;

Kulkarni, GU .

MATERIALS RESEARCH BULLETIN, 1998, 33 (08) :1185-1194

← 1 2 3 4 5 →