How do oxidized thiolate ligands affect the electronic and reactivity properties of a nitrile hydratase model compound?

被引：60

作者：

Kung, I ^{[1
]}

Schweitzer, D ^{[1
]}

Shearer, J ^{[1
]}

Taylor, WD ^{[1
]}

Jackson, HL ^{[1
]}

Lovell, S ^{[1
]}

Kovacs, JA ^{[1
]}

机构：

[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2000年 / 122卷 / 34期

关键词：

D O I：

10.1021/ja0017561

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：8299 / 8300

页数：2

共 22 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].

ADDISON, AW ;

RAO, TN ;

REEDIJK, J ;

VANRIJN, J ;

VERSCHOOR, GC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356

[2] SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF COORDINATED SULFENIC ACIDS [J].

ADZAMLI, IK ;

LIBSON, K ;

LYDON, JD ;

ELDER, RC ;

DEUTSCH, E .

INORGANIC CHEMISTRY, 1979, 18 (02) :303-311

[3] Mono- and dinuclear transition metal complexes of the hexadentate ligand tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane (L) [J].

Beissel, T ;

Glaser, T ;

Kesting, F ;

Wieghardt, K ;

Nuber, B .

INORGANIC CHEMISTRY, 1996, 35 (13) :3936-3947

[4] STUDY OF SULFINATE AND SULFENATE COMPLEXES DERIVED FROM THE OXYGENATION OF THIOLATE SULFUR IN [1,5-BIS(2-MERCAPTO-2 METHYLPROPYL)-1,5-DIAZACYCLOOCTANATO(2-)]NICKEL(II) [J].

BUONOMO, RM ;

FONT, I ;

MAGUIRE, MJ ;

REIBENSPIES, JH ;

TUNTULANI, T ;

DARENSBOURG, MY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (03) :963-973

[5] Protein-sulfenic acids: Diverse roles for an unlikely player in enzyme catalysis and redox regulation [J].

Claiborne, A ;

Yeh, JI ;

Mallett, TC ;

Luba, J ;

Crane, EJ ;

Charrier, V ;

Parsonage, D .

BIOCHEMISTRY, 1999, 38 (47) :15407-15416

[6] Oxidation of a vanadium(V)-dithiolate complex to a vanadium(V)-eta(2),eta(2)-disulfenate complex [J].

Cornman, CR ;

Stauffer, TC ;

Boyle, PD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (25) :5986-5987

[7] Reactivity of five-coordinate models for the thiolate-ligated Fe site of nitrile hydratase [J].

Ellison, JJ ;

Nienstedt, A ;

Shoner, SC ;

Barnhart, D ;

Cowen, JA ;

Kovacs, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (23) :5691-5700

[8] A SQUARE-PLANAR COBALT(III) TETRATHIOLATE COMPLEX [J].

FIKAR, R ;

KOCH, SA ;

MILLAR, MM .

INORGANIC CHEMISTRY, 1985, 24 (21) :3311-3312

[9] Oxygen capture by sulfur in nickel thiolates [J].

Grapperhaus, CA ;

Darensbourg, MY .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (08) :451-459

[10]

Heinrich L, 1999, ANGEW CHEM INT EDIT, V38, P3526, DOI 10.1002/(SICI)1521-3773(19991203)38:23<3526::AID-ANIE3526>3.0.CO

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