Palladium-Catalyzed Carbonylation Reactions of Alkenes and Alkynes

被引：377

作者：

Brennfuehrer, Anne ^{[1
]}

Neumann, Helfried ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

CHEMCATCHEM | 2009年 / 1卷 / 01期

关键词：

alkenes; alkynes; carbon monoxide; carbonylation; palladium; ENANTIOSELECTIVE BIS-ALKOXYCARBONYLATION; NOBLE METAL COMPOUNDS; INTRAMOLECULAR ALKOXYPALLADATION CARBONYLATION; CO-ETHYLENE COPOLYMERIZATION; 7-MEMBERED RING LACTONES; P-TOLUENESULFONIC ACID; X-RAY-STRUCTURE; CARBON-MONOXIDE; TERMINAL ALKYNES; ORGANIC SYNTHESES;

D O I：

10.1002/cctc.200900062

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Palladium-catalyzed carbonylation reactions of alkenes and alkynes with different nucleophiles have undergone rapid development ever since the seminal work of Reppe back in the 1930s. Nowadays, a plethora of palladium catalysts and various synthetic protocols are available for the synthesis of valuable carboxylic acids and acrylic acids as well as their derivatives. Herein, we summarize the recent catalyst developments and selected organic applications in this area.

引用

页码：28 / 41

页数：14

共 278 条

[1] Hydrocarboxylation of styrene in aqueous media with Pd-guanidinumphosphine systems [J].

Aghmiz, A ;

Giménez-Pedrós, M ;

Masdeu-Bultó, AM ;

Schmidtchen, FP .

CATALYSIS LETTERS, 2005, 103 (3-4) :191-193

[2] Catalytic hydrocarboxylation and hydroesterification reactions of 1,2-polybutadiene [J].

Ajjou, AN ;

Alper, H .

MACROMOLECULES, 1996, 29 (05) :1784-1788

[3] Regioselective hydroesterification of 1-alkynes catalyzed by palladium-phosphine complexes [J].

Akao, M ;

Sugawara, S ;

Amino, K ;

Inoue, Y .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 157 (1-2) :117-122

[4] SELECTIVE HYDROESTERIFICATION OF ALKYNES TO MONOESTERS OR DIESTERS [J].

ALPER, H ;

DESPEYROUX, B ;

WOELL, JB .

TETRAHEDRON LETTERS, 1983, 24 (51) :5691-5694

[5] REGIOSPECIFIC ALKYNE FORMATE ESTER REACTIONS CATALYZED BY PALLADIUM(0) [J].

ALPER, H ;

SALDANAMALDONADO, M ;

LIN, IJB .

JOURNAL OF MOLECULAR CATALYSIS, 1988, 49 (01) :L27-L30

[6] ASYMMETRIC-SYNTHESIS OF ACIDS BY THE PALLADIUM-CATALYZED HYDROCARBOXYLATION OF OLEFINS IN THE PRESENCE OF (R)-(-)-1,1'-BINAPHTHYL-2,2'-DIYL OR (S)-(+)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE [J].

ALPER, H ;

HAMEL, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (07) :2803-2804

[7] PALLADIUM-CATALYZED CONVERSION OF ALKENOLS INTO 5-MEMBERED AND 6-MEMBERED RING LACTONES AT ROOM-TEMPERATURE AND ATMOSPHERIC-PRESSURE [J].

ALPER, H ;

LEONARD, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (08) :511-512

[8] FACILE OXIDATIVE CYCLIZATION AND CARBONYLATION OF ALLYLIC ALCOHOLS [J].

ALPER, H ;

LEONARD, D .

TETRAHEDRON LETTERS, 1985, 26 (46) :5639-5642

[9] PALLADIUM-CATALYZED ALKYNE OXALATE ESTER REACTION - A FORMAL CARBON CARBON BOND-CLEAVAGE PROCESS [J].

ALPER, H ;

SALDANAMALDONADO, M .

ORGANOMETALLICS, 1989, 8 (04) :1124-1125

[10]

ALPER H, 1990, CHEM COMMUN, P135

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