Co-doped anatase TiO2 nanofibers fabricated by electrospinning

被引:13
作者
Jia, C. W. [1 ]
Xie, E. Q. [1 ]
Zhao, J. G. [1 ]
Duan, H. G. [1 ]
机构
[1] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China
关键词
D O I
10.1063/1.2724535
中图分类号
O59 [应用物理学];
学科分类号
摘要
Co-doped TiO2 nanofibers with an average diameter of similar to 70 nm were fabricated with electrospinning method. X-ray diffraction measurements show that the nanofibers possess pure anatase structure. The obtained nanofibers exhibit evident room temperature ferromagnetism through magnetic measurement. The photoluminescence of the Co-doped TiO2 nanofibers is composed of two emission bands attributed to self-trapped excitons and oxygen vacancies, different from that of pure TiO2 nanofibers which only includes emission due to self-trapped excitons. Photoluminescence intensity due to oxygen vacancies vary with annealing atmosphere and Co concentration, and the ferromagnetic moment increases with the increment of oxygen vacancies. (C) 2007 American Institute of Physics.
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页数:4
相关论文
共 21 条
[1]
Activation of high-Tc ferromagnetism in Co2+:TiO2 and Cr3+:TiO2 nanorods and nanocrystals by grain boundary defects [J].
Bryan, JD ;
Santangelo, SA ;
Keveren, SC ;
Gamelin, DR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (44) :15568-15574
[2]
Strong room-temperature ferromagnetism in Co2+-doped TiO2 made from colloidal nanocrystals [J].
Bryan, JD ;
Heald, SM ;
Chambers, SA ;
Gamelin, DR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (37) :11640-11647
[3]
Clusters and magnetism in epitaxial Co-doped TiO2 anatase [J].
Chambers, SA ;
Droubay, T ;
Wang, CM ;
Lea, AS ;
Farrow, RFC ;
Folks, L ;
Deline, V ;
Anders, S .
APPLIED PHYSICS LETTERS, 2003, 82 (08) :1257-1259
[4]
TEMPERATURE-DEPENDENCE OF THE LUMINESCENCE OF TIO2 POWDER [J].
FORSS, L ;
SCHUBNELL, M .
APPLIED PHYSICS B-PHOTOPHYSICS AND LASER CHEMISTRY, 1993, 56 (06) :363-366
[5]
FURDYNA JK, 1988, SEMICONDUCTOR SEMIME, V25
[6]
Cobalt-doped anatase TiO2:: A room temperature dilute magnetic dielectric material -: art. no. 10D320 [J].
Griffin, KA ;
Pakhomov, AB ;
Wang, CM ;
Heald, SM ;
Krishnan, KM .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (10)
[7]
Structural and optical properties of Ti1-xCoxO2 films prepared by sol-gel spin coating [J].
Huang, CM ;
Guo, YP ;
Liu, XQ ;
Wang, YY .
THIN SOLID FILMS, 2006, 505 (1-2) :141-144
[8]
Oxygen vacancies and ferromagnetism in CoxTi1-xO2-x-y -: art. no. 073908 [J].
Jaffe, JE ;
Droubay, TC ;
Chambers, SA .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (07)
[9]
Spectral narrowing of self-trapped exciton emission in anatase thin films [J].
Kiisk, V ;
Sildos, I ;
Suisalu, A ;
Aarik, J .
THIN SOLID FILMS, 2001, 400 (1-2) :130-133
[10]
Preparation and photoluminescence of highly ordered TiO2 nanowire arrays [J].
Lei, Y ;
Zhang, LD ;
Meng, GW ;
Li, GH ;
Zhang, XY ;
Liang, CH ;
Chen, W ;
Wang, SX .
APPLIED PHYSICS LETTERS, 2001, 78 (08) :1125-1127