Quaternary onium tribromide catalyzed cyclic carbonate synthesis from carbon dioxide and epoxides

被引:107
作者
Chang, Tao [1 ]
Jing, Huanwang [1 ]
Jin, Lili [1 ]
Qiu, Wenyuan [1 ]
机构
[1] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
基金
中国国家自然科学基金;
关键词
carbon dioxides; epoxides; quaternary onium tribromide; coupling reaction; chiral propylene carbonate;
D O I
10.1016/j.molcata.2006.08.089
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Novel and efficient organic catalysts of quaternary onium tribromide and the related metal-containing catalysts of SalenCoX/PTAT were developed to catalyze the coupling reaction of carbon dioxide and epoxides generating relevant cyclic carbonates including chiral propylene carbonate under extremely mild condition. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:241 / 247
页数:7
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