Vibrational relaxation of the H2O bending mode in liquid water

被引：59

作者：

Larsen, OFA ^{[1
]}

Woutersen, S ^{[1
]}

机构：

[1] FOM, Inst Atom & Mol Phys, NL-1098 SJ Amsterdam, Netherlands

来源：

JOURNAL OF CHEMICAL PHYSICS | 2004年 / 121卷 / 24期

关键词：

D O I：

10.1063/1.1839175

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have studied the vibrational relaxation of the H2O bending mode in an H2O:HDO:D2O isotopic mixture using infrared pump-probe spectroscopy. The transient spectrum and its delay dependence reveal an anharmonic shift of 55+/-10 cm(-1) for the H2O bending mode, and a value of 400+/-30 fs for its vibrational lifetime. (C) 2004 American Institute of Physics.

引用

页码：12143 / 12145

页数：3

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