Classical kinetics of catalytic reactions

被引：99

作者：

Djéga-Mariadassou, G

Boudart, M

机构：

[1] Univ Paris 06, Lab React Surface, UMR 7609, CNRS, F-75252 Paris 05, France

[2] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA

来源：

JOURNAL OF CATALYSIS | 2003年 / 216卷 / 1-2期

关键词：

assisted catalytic reactions; kinetic coupling; rate constants; rates and selectivity;

D O I：

10.1016/S0021-9517(02)00099-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The present paper deals with a "reactivity approach" to complex catalytic reactions. It utilizes data obtained with a reactor and demonstrates the very important role of both rate constants and concentrations of adsorbed species, on catalytic cycle, activity, and selectivity. It develops a link between global kinetics and closed sequence of elementary steps. It emphasizes the aspects of "assisted" catalytic reactions, kinetic "coupling" of catalytic cycles, and selectivity. (C) 2003 Elsevier Science (USA). All rights reserved.

引用

页码：89 / 97

页数：9

共 46 条

[1] SIMULTANEOUS KINETIC AND INFRARED SPECTRAL STUDIES OF CARBON MONOXIDE OXIDATION ON PALLADIUM UNDER STEADY-STATE CONDITIONS [J].