Electronic properties of metal nanorods probed by surface-enhanced Raman spectroscopy

被引：26

作者：

Yao, JL

Xu, X

Wu, DY

Xie, Y

Ren, B

Tian, ZQ ^{[1
]}

Pan, GP

Sun, DM

Xue, KH

机构：

[1] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

[2] Xiamen Univ, Inst Phys Chem, Xiamen 361005, Peoples R China

[3] Nanjing Normal Univ, Dept Chem, Nanjing 210097, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 17期

关键词：

D O I：

10.1039/b002717k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Applying the probe molecule strategy, surface-enhanced Raman spectroscopy has been used, for the first time, as a diagnostic tool of the electronic properties of metal nanorods; the vibrational frequency of the probe molecule SCN- at Cu nanorods is shown to critically depend on the nanorod's diameter in the range from 50 to 15 nm; the up-shifting of the Fermi level with a decrease of the nanorod's diameter is interpreted based on the change of cohesive energy owing to the high ratio of surface to bulk atoms.

引用

页码：1627 / 1628

页数：2

共 15 条

[1] Visible region polarization spectroscopic studies of template-synthesized gold nanoparticles oriented in polyethylene [J].