An N,P-disubstituted-2-aminophosphaalkene and lithium and potassium complexes of the deprotonated "phosphaamidinate" anion

被引：20

作者：

Boeré, RT ^{[1
]}

Cole, ML

Junk, PC

Masuda, JD

Wolmershäuser, G

机构：

[1] Univ Lethbridge, Dept Chem & Biochem, Lethbridge, AB T1K 3M4, Canada

[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[3] Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 22期

关键词：

D O I：

10.1039/b408994d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of DippPH(2) ( Dipp = 2,6-(Pr2C6H3)-Pr-i) with DippN=C(p-CH3C6H4)Cl in refluxing xylenes affords DippP=C(p-CH3C6H4)N(H) Dipp; deprotonation with alkali metal reagents produces unique lithium and potassium complexes with the ligand in a different geometry to that of the free phosphaamidine.

引用

页码：2564 / 2565

页数：2

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