Allosteric silver(I) ion binding with peripheral π clefts of a Ce(IV) double decker porphyrin

被引：64

作者：

Ikeda, M ^{[1
]}

Tanida, T ^{[1
]}

Takeuchi, M ^{[1
]}

Shinkai, S ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 13期

关键词：

D O I：

10.1021/ol005807a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A cerium(IV) double decker porphyrin (1) bearing four 4-methoxyphenyl groups was synthesized. Compound 1 shows a positive, homotoropic allosteric effect in metal recognition of Ag+ ion, and the peripheral pi clefts of 1 act as effective binding sites for Ag+ ion.

引用

页码：1803 / 1805

页数：3

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