Hydrogen generation from ethanol in supercritical water without catalyst

被引：90

作者：

Arita, T

Nakahara, K

Nagami, K

Kajimoto, O

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

[2] Suntory Ltd, Inst Fundamental Res, Osaka 6188503, Japan

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 05期

关键词：

supercritical water; ethanol; decomposition; dehydroxylation; wall effect; oxidation;

D O I：

10.1016/S0040-4039(02)02704-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Without oxidizing reagents or catalysts, ethanol was smoothly converted to CH(3)CHO and H(2) in supercritical water at 450-500degreesC. CH(3)CHO was further decomposed into CH(4) and CO instead of being oxidized into acetic acid. These features suggest the direct participation of water molecules in the ethanol dehydrogenation. (C) 2003 Elsevier Science Ltd. All rights reserved.

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页码：1083 / 1086

页数：4

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