Highly conjugated, water-soluble polymers via the direct oxidative polymerization of monosubstituted bithiophenes

被引：14

作者：

Rasmussen, SC

Pickens, JC

Hutchison, JE ^{[1
]}

机构：

[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA

[2] Univ Oregon, Inst Mat Sci, Eugene, OR 97403 USA

来源：

MACROMOLECULES | 1998年 / 31卷 / 03期

关键词：

D O I：

10.1021/ma970767k

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new carboxylate derivatized polythiophene, poly(4-carboxy-2,2′-bithiophene) obtained through the direct chemical or electrochemical oxidation of 4-carboxy-2,2′-bithiophene is discussed. The utility and advantages of preparing functionalized polythiophenes from 4-substituted-2,2′-bithiophenes are described. The new method modifies the properties of the polymers while reducing side chain interactions and allows facile incorporation of strong electron-withdrawing side chains.

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收藏

页码：933 / 936

页数：4

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