Synthesis of 1,2-diheteroatom-substituted alkenes via rhodium-catalyzed intramolecular hydrogen transfer

被引：19

作者：

Diaz-Requejo, MM ^{[1
]}

DiSalvo, D ^{[1
]}

Brookhart, M ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 08期

关键词：

D O I：

10.1021/ja029393n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

While 1,2-diheteroatom-substituted alkenes represent useful synthetic building blocks, there are no simple, general procedures available for preparation of such compounds. We describe here a simple catalytic procedure based on rhodium C-H bond activation for the synthesis of diheteroatom alkenes of the type R3SiOCH=CHG (G = -OR, -NRR-). Copyright © 2003 American Chemical Society.

引用

页码：2038 / 2039

页数：2

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