'Inverse crown ether' complexes extended to group 12 through the syntheses of [Na2Zn2(HMDS)4(O)] and [{K2Zn2(HMDS)4(O2)x(O)y}∞]

被引:55
作者
Forbes, GC
Kennedy, AR [1 ]
Mulvey, RE
Rowlings, RB
Clegg, W
Liddle, ST
Wilson, CC
机构
[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland
[2] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
[3] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England
关键词
D O I
10.1039/b005233g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first sodium-zinc and potassium-zinc members of the inverse crown ether family, an emerging class of heterometallic macrocyclic amides previously limited to alkali metal-magnesium combinations, have been synthesised and crystallographically characterised.
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页码:1759 / 1760
页数:2
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