Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C-N bond

被引：56

作者：

Gandelman, M ^{[1
]}

Milstein, D ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 17期

关键词：

D O I：

10.1039/b004820h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [RhCl(COE)(2)](2) with an excess of the aromatic aminophosphine 1-(diethylaminomethyl)-3-(di-tert-butylphosphinomethyl)-2,4,6-trimethylbenzene (2) in dioxane under mild H-2 pressure results in selective catalytic activation of an unstrained C-N single bond.

引用

页码：1603 / 1604

页数：2

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