Generation of nitrile N-selenides, RCNSe, as neutrals and radical cations in the gas phase

被引：20

作者：

Gerbaux, P

Flammang, R ^{[2
]}

Morkved, EH

Wong, MW

Wentrup, C

机构：

[1] Norwegian Univ Sci & Technol, Dept Organ Chem, N-7034 Trondheim, Norway

[2] Univ Mons, Organ Chem Lab, B-7000 Mons, Belgium

[3] Natl Univ Singapore, Dept Chem, Singapore 117548, Singapore

[4] Univ Queensland, Dept Chem, St Lucia, Qld 4067, Australia

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 07期

关键词：

D O I：

10.1016/S0040-4039(97)10228-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyanogen N-selenide radical cation, NCCNSe.+, is prepared by dissociative ionization of 3,4-dicyano-1,2,5-selenadiazole [1]. It reacts readily with nitriles in the gas phase to produce nitrile N-selenide ions, RCNSe.+. The stability of the corresponding neutral dipoles is confirmed by neutralization-reionization mass spectrometric experiments. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：533 / 536

页数：4

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