Copper diffusion in ZnS thin films

被引:28
作者
Bacaksiz, E
Dzhafarov, TD
Novruzov, VD
Öztürk, K
Tomakin, M
Küçükömeroglu, T
Altunbas, M [1 ]
Yanmaz, E
Abay, B
机构
[1] Karadeniz Tech Univ, Dept Phys, Fac Arts & Sci, TR-61080 Trabzon, Turkey
[2] Yildiz Tech Univ, Dept Phys, Fac Arts & Sci, TR-34210 Istanbul, Turkey
[3] Karadeniz Tech Univ, Dept Phys, Fac Arts & Sci, Rize, Turkey
[4] Karadeniz Tech Univ, Dept Mech Engn, Fac Engn & Architecture, TR-61080 Trabzon, Turkey
[5] Ataturk Univ, Dept Phys, Fac Arts & Sci, Erzurum, Turkey
来源
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2004年 / 201卷 / 13期
关键词
D O I
10.1002/pssa.200306853
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Diffusion of Cu in ZnS thin films was investigated in the temperature range 80-400degreesC using the energy-dispersive X-ray fluorescence (EDXRF) technique. ZnS thin films were deposited by spray pyrolysis on a glass substrate. The temperature dependence of the Cu diffusion coefficient is described by the equation D = 1.4 x 10(-10) exp [-(0.18 eV)/kT]. It is shown that diffusion doping of n-type ZnS by Cu is accompanied by a significant increase in resistivity and a slight decrease in the band gap of the ZnS films. The observed results are attributed to the migration of Cu in polycrystalline ZnS films by means of diffusion both along grain boundaries and into grains. (C) 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2948 / 2952
页数:5
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