Xenon as a complex ligand:: The tetra xenono gold(II) cation in AuXe42+(Sb2F11-)2

被引：270

作者：

Seidel, S ^{[1
]}

Seppelt, K ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Chem, D-14195 Berlin, Germany

来源：

SCIENCE | 2000年 / 290卷 / 5489期

关键词：

D O I：

10.1126/science.290.5489.117

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The first metal-xenon compound with direct gold-xenon bonds is achieved by reduction of AuF3 with elemental xenon. The square planar AuXe42+ cation is established by a single-crystal structure determination, with a gold-xenon bond Length of approximately 274 picometers. The bonding between gold and xenon is of the a donor type, resulting in a charge of approximately 0.4 per xenon atom.

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页码：117 / 118

页数：2

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