Accurate quartic and sextic centrifugal distortion constants of CH3CP

被引：8

作者：

Bizzocchi, L ^{[1
]}

Cludi, L ^{[1
]}

Degli Esposti, C ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2003年 / 218卷 / 01期

关键词：

D O I：

10.1016/S0022-2852(02)00080-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

1-Phosphapropyne has been produced in the gas phase by pyrolysis of a mixture of ethane and phosphorus trichloride. The ground state rotational spectra of the most abundant isotopomer and of the isotopic variants (CH3CP)-C-13 and (CH3CP)-C-13 have been investigated in the millimeter and submillimeter wave regions obtaining very accurate values of the quartic centrifugal distortion constants D-J and D-JK and of the sextic distortion constants H-JK and H-KJ. (C) 2003 Elsevier Science (USA). All rights reserved.

引用

页码：53 / 57

页数：5

共 12 条

[1] Millimeter-wave spectroscopy of HC3P isotopomers and coupled-cluster calculations:: the molecular structure of phosphabutadiyne [J].

Bizzocchi, L ;

Degli Esposti, C ;

Botschwina, P .

CHEMICAL PHYSICS LETTERS, 2000, 319 (3-4) :411-417

[2] Pyrolysis of sulfur tetrafluoride over boron: Excited-state rotational spectra and equilibrium structure of fluorothioborine (FBS) [J].

Bizzocchi, L ;

Esposti, CD .

JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (15) :7041-7050

[3] Millimeter-wave spectroscopy and coupled cluster calculations for NCCP [J].

Bizzocchi, L ;

Esposti, CD ;

Botschwina, P .

JOURNAL OF CHEMICAL PHYSICS, 2000, 113 (04) :1465-1472

[4] THE SUBMILLIMETER-WAVE ROTATIONAL SPECTRUM OF METHYL CYANIDE - ANALYSIS OF THE GROUND AND THE LOW-LYING EXCITED VIBRATIONAL-STATES [J].

BOCQUET, R ;

WLODARCZAK, G ;

BAUER, A ;

DEMAISON, J .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1988, 127 (02) :382-389

[5] SYNTHESIS AND CHARACTERIZATION OF ETHYLIDYNEARSINE [J].

GUILLEMIN, JC ;

LASSALLE, L ;

DREAN, P ;

WLODARCZAK, G ;

DEMAISON, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) :8930-8936

[6] DETECTION OF REACTIVE MOLECULE 1-PHOSPHAPROPYNE, CH3C=P, BY MICROWAVE SPECTROSCOPY [J].

HOPKINSON, MJ ;

KROTO, HW ;

NIXON, JF ;

SIMMONS, NPC .

CHEMICAL PHYSICS LETTERS, 1976, 42 (03) :460-461

[7] MICROWAVE-SPECTRUM OF 1-PHOSPHAPROPYNE, CH3C=P - MOLECULAR-STRUCTURE, DIPOLE-MOMENT, AND VIBRATION-ROTATION ANALYSIS [J].

KROTO, HW ;

NIXON, JF ;

SIMMONS, NPC .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1979, 77 (02) :270-285

[8] THE NU-2-INFRARED BAND OF 1-PHOSPHAPROPYNE CH3C=P [J].

OHNO, K ;

MATSUURA, H ;

MCNAUGHTON, D ;

KROTO, HW .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1987, 124 (01) :82-91

[9] THE NU-6 INFRARED BAND OF 1-PHOSPHAPROPYNE CH3C=P [J].

OHNO, K ;

MATSUURA, H ;

MCNAUGHTON, D ;

KROTO, HW .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1987, 126 (02) :245-254

[10] INFRARED STUDY ON THE C=P STRETCHING VIBRATION OF 1-PHOSPHAPROPYNE CH3C=P AND ITS PERDEUTERIUM ANALOG CD3C=P [J].

OHNO, K ;

YAMAMOTO, Y ;

MATSUURA, H ;

MURATA, H .

CHEMISTRY LETTERS, 1984, (03) :413-414

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