Doping-dedoping-driven optic effect of π-conjugated polymers prepared in cholesteric-liquid-crystal electrolytes

被引：49

作者：

Goto, Hiromasa ^{[1
]}

机构：

[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Inst Sci Mat, Tsukuba, Ibaraki 3058573, Japan

来源：

PHYSICAL REVIEW LETTERS | 2007年 / 98卷 / 25期

关键词：

D O I：

10.1103/PhysRevLett.98.253901

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Chiral conjugated polymers were synthesized by electrochemical polymerization in a cholesteric-liquid-crystal (CLC) electrolyte. The polymers display a characteristic finger print texture similar to that of CLC. The natural optical activity of the polymers was successfully controlled by the electrochemical doping-dedoping procedure. The finding of this unprecedented mechanism, involving doping of pi-conjugated systems, can be an important advance in the development of plastic optoelectronics based on conductive polymers.

引用

页数：4

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