Gold nanoparticles from self-assembled gold(I) amine precursors

被引:107
作者
Gomez, S
Philippot, K
Collière, V
Chaudret, B
Senocq, F
Lecante, P
机构
[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 04, France
[2] ENSCT, CIRIMAT, CNRS, UMR 5085, F-31077 Toulouse, France
[3] CNRS, Ctr Elaborat Mat & Etud Struct, F-31055 Toulouse 04, France
关键词
D O I
10.1039/b005327i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of AuCl(THT) (1) with long chain primary amines (CnH2n+1NH2; n = 8, 12, 16) leads to the formation of the complexes AuCl(NH2R) (R = C8H17, 2; C12H25, 3; C16H33, 4) which are characterized by classical methods and shown to self-organize in the solid state into a fibrous material; decomposition of the complexes inside the supramolecular framework yields a monolayer of ordered gold nanoparticles.
引用
收藏
页码:1945 / 1946
页数:2
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