Regio/diastereo-controls of the Bingel-type biscyclopropanation of [60]fullerene by using bismalonates with a Troger base analogue-derived tether

被引：34

作者：

Ishida, Y ^{[1
]}

Ito, H ^{[1
]}

Mori, D ^{[1
]}

Saigo, K ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 01期

关键词：

bifunctionalizatiion; Bingel reaction; fullerene; heteroaromattic ring; template synthesis; Troger base;

D O I：

10.1016/j.tetlet.2004.11.022

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Four kinds of bismalonates tethered with a Troger base derivative were synthesized and used for the double Bingel reaction of [60]fullerene. the regio/diastereoselectivities of the reaction were highly influenced by the structure of the Troger base derivatives. Heteroaromatic analogues of the Troger base were found to be applicable as the core the the tether. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：109 / 112

页数：4

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