Photocurable carbonate-selective membranes for chemical sensors containing lipophilic additives

被引：25

作者：

Levitchev, SS ^{[1
]}

Smirnova, AL ^{[1
]}

Khitrova, VL ^{[1
]}

Lvova, LB ^{[1
]}

Bratov, AV ^{[1
]}

Vlasov, YG ^{[1
]}

机构：

[1] St Petersburg State Univ, Dept Chem, Lab Chem Sensors, St Petersburg 198904, Russia

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 1997年 / 44卷 / 1-3期

关键词：

ion-selective electrode; lipophilic additives; membrane; photocurable; potentiometry; sensor;

D O I：

10.1016/S0925-4005(97)00232-3

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The potentiometric properties of carbonate sensors with photocurable membranes based on polyurethane and polyvinyl chloride (PVC) membranes containing tetradecylammonium carbonate and hexyl-p-trifluoroacetylbenzoate are examined. The properties of these membranes with different concentrations of plasticizer (dioctylphtalate) are investigated. The difference between the electrodes based on photocurable polymer and PVC membranes is shown. In the case of low concentrations of plasticizer, the comparison of the photocurable membranes with PVC ones shows higher slope and selectivity. The influence of lipophilic additive is studied. It is shown that the presence of anionic sites inside the membrane improves the potentiometric properties of photocurable carbonate-selective electrodes. (C) 1997 Elsevier Science S.A.

引用

页码：397 / 401

页数：5

共 12 条

[1] POTENTIOMETRIC ANION SELECTIVITY OF POLYMER MEMBRANES DOPED WITH PALLADIUM ORGANOPHOSPHINE COMPLEX [J].

BADR, IHA ;

MEYERHOFF, ME ;

HASSAN, SSM .

ANALYTICAL CHEMISTRY, 1995, 67 (15) :2613-2618

[2]

BATES RG, 1964, DETERMINATION PH, P300

[3]

Dusek K, 1971, POLYM NETWORKS STRUC, P245

[4] PREPARATION AND PROPERTIES OF A CARBONATE ION-SELECTIVE MEMBRANE ELECTRODE [J].

HERMAN, HB ;

RECHNITZ, GA .

ANALYTICA CHIMICA ACTA, 1975, 76 (01) :155-164

[5]

LEVICHEV SS, 1994, SENSOR ACTUAT B-CHEM, V18, P625

[6] ROLE OF TRIFLUOROACETOPHENONE SOLVENTS AND QUATERNARY AMMONIUM-SALTS IN CARBONATE-SELECTIVE LIQUID MEMBRANE ELECTRODES [J].

MEYERHOFF, ME ;

PRETSCH, E ;

WELTI, DH ;

SIMON, W .

ANALYTICAL CHEMISTRY, 1987, 59 (01) :144-150

[7] IONIC ADDITIVES FOR ION-SELECTIVE ELECTRODES BASED ON ELECTRICALLY CHARGED CARRIERS [J].

SCHALLER, U ;

BAKKER, E ;

SPICHIGER, UE ;

PRETSCH, E .

ANALYTICAL CHEMISTRY, 1994, 66 (03) :391-398

[8] CARRIER MECHANISM OF ACIDIC IONOPHORES IN SOLVENT POLYMERIC MEMBRANE ION-SELECTIVE ELECTRODES [J].

SCHALLER, U ;

BAKKER, E ;

PRETSCH, E .

ANALYTICAL CHEMISTRY, 1995, 67 (18) :3123-3132

[9]

Smirnova A.L, 1988, ELEKTROKHIMIYA, V24, P1187

[10]

SMIRNOVA AL, 1985, ELEKTROKHIMIYA, V21, P1335

← 1 2 →