Ansa-bis(cyclopentadienyl) complexes of niobium(III) and niobium(IV); X-ray structures of [Nb(eta-C5H4-CMe2-eta-C5H4)(eta(2)-BH4)] and [Nb(eta-C5H4-CMe2-eta-C5H4)(H)PMe3]

被引:18
作者
Bailey, NJ
Green, MLH
Leech, MA
Saunders, JF
Tidswell, HM
机构
[1] UNIV OXFORD, INORGAN CHEM LAB, OXFORD OX1 3QR, ENGLAND
[2] CHEM CRYSTALLOG LAB, OXFORD OX1 3PD, ENGLAND
关键词
ansa; cyclopentadienyl; niobium; group; 5;
D O I
10.1016/S0022-328X(96)06911-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The new compounds [Nb(eta-C5H4-CMe2-eta-C5H4)Cl-2], [Nb(eta-C5H4-CMe2-eta-C5H4)(eta(2)-BH4)]*, [Nb(eta-C5H4-CMe2-eta-C5H4)(H)PR3] (R = Me, Ph) and [Nb(eta-C5H4-CMe2-eta-C5H4)(SPh)(2)] have been prepared. An asterisk indicates that the X-ray crystal structure has been determined.
引用
收藏
页码:111 / 118
页数:8
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