Electrochemical polymerization of acrylics on stainless steel cathodes

被引：20

作者：

Cram, SL

Spinks, GM

Wallace, GG

Brown, HR

机构：

[1] Univ Wollongong, Intelligent Polymer Res Inst, Wollongong, NSW 2522, Australia

[2] Univ Wollongong, Inst Steel Proc & Prod, Wollongong, NSW 2522, Australia

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2003年 / 87卷 / 05期

关键词：

thin films; electron microscopy; FT-IR; morphology;

D O I：

10.1002/app.11436

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A cathodic, aqueous-based technique for producing uniform, thin, passive films of poly(methyl methacrylate) and poly(glycidylacrylate) on stainless steel electrodes was developed. The films were chemically characterized by Fourier transform infrared spectroscopy, NMR spectroscopy, and differential scanning calorimetry. The thickness (quantified by ellipsometry) and morphology of the films were dependent on the electrolysis time and potential and were also influenced by the individual monomer properties. (C) 2002 Wiley Periodicals, Inc.

引用

页码：765 / 773

页数：9

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