Supramolecular self-assembly of three-dimensional nanostructures and microstructures: Microcapsules from electroactive and photoactive rod-coil-rod triblock copolymers

被引:119
作者
Chen, XL [1 ]
Jenekhe, SA [1 ]
机构
[1] Univ Rochester, Dept Chem Engn, Rochester, NY 14627 USA
关键词
D O I
10.1021/ma000100p
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this study, the synthesis and supramolecular self-assembly of a novel rod triblock copolymer architecture with the general structure A-NHCO-B-CONH-A were carried out. The new quinoline-styrene-quinoline (QSQ) triblock copolymers were found to spontaneously form robust microcapsules or spherical vesicles in solution. The supramolecular morphology was revealed by polarized optical, fluorescence optical, and scanning electron microscopies.
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页码:4610 / 4612
页数:3
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