Unexpected isolation, and structural characterization, of a β-hydrogen-containing σ-alkylpalladium halide complex in the course of an intramolecular Heck reaction.: Synthesis of polycyclic isoquinoline derivatives

被引:35
作者
Clique, B [1 ]
Fabritius, CH [1 ]
Couturier, C [1 ]
Monteiro, N [1 ]
Balme, G [1 ]
机构
[1] Univ Lyon 1, CNRS, UMR 5622, Lab Chim Organ 1, F-69622 Villeurbanne, France
关键词
D O I
10.1039/b211856b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The isolation of a stable beta-hydrogen-containing R-PdLn-X complex (R = alkyl; X = halide) issued from a Heck reaction is reported together with some aspects of its reactivity.
引用
收藏
页码:272 / 273
页数:2
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