Macropolyhedral boron-containing cluster chemistry.: Triple cluster fusion and the molecular structure of [(PMe3)2IrB26H24Ir(CO)(PMe3)2].: A 28-vertex metallaborane cluster with a polyboron core

被引：18

作者：

Bould, J

Kennedy, JD ^{[1
]}

Barton, L

Rath, NP

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[2] Univ Missouri, Dept Chem, St Louis, MO 63121 USA

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 24期

关键词：

D O I：

10.1039/a706905g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[(PMe3)(2)IrB26H24Ir(CO)(PMe3)(2)], from the thermolysis of [(CO)(PMe3)(2)HIrB8H12] in molten B10H14, is a triple-cluster species that consists of close twelve-vertex {IrB11} and closo ten-vertex {IrB9} units fused by (a) a common {IrB2} triangular face and (b) by an adjacent 'wedge' interboron linkage that also binds a nido nine-vertex {IrB8} subcluster; the resulting {Ir2B26} cluster has a novel five-boron core.

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页码：2405 / 2406

页数：2

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