Compact methanol reformer test for fuel-cell powered light-duty vehicles

被引:81
作者
Emonts, B
Hansen, JB
Jorgensen, SL
Hohlein, B
Peters, R
机构
[1] Forschungszentrum Julich, Inst Energieverfahrenstech, D-52425 Julich, Germany
[2] Haldor Topsoe Res Labs, DK-2800 Lyngby, Denmark
关键词
compact methanol reformer; fuel-cell powered light-duty vehicles; low-temperature fuel cells; catalytic burner; hydrogen permeable membrane; full fuel cycle;
D O I
10.1016/S0378-7753(97)02724-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
On-board production of hydrogen from methanol based on a steam reformer in connection with the use of low-temperature fuel-cells (PEMFC) is an attractive option as energy conversion unit for light-duty vehicles. A steam reforming process at higher pressures with an external burner offers advantages in comparison to a steam reformer with integrated partial oxidation in lens of total efficiency for electricity production. The main aim of a common project carried out by the Forschungszentrum Julich (FZJ), Haldor Topsoe A/S (HTAS) and Siemens AG is to design, to construct and to test a steam reformer reactor concept (HTAS) with external catalytic burner (FZJ) as heat source as well as catalysts for heterogeneously catalyzed hydrogen production (HTAS). concepts for gas treatment (HTAS, FZJ) and a low-temperature fuel cell (Siemens). Based on the experimental results obtained so far concerning methanol reformers, catalytic burners and gas conditioning units, our report describes the total system, a test unit and preliminary test results related to a hydrogen production capacity of 50 kW (LHV) and dynamic operating conditions. This hydrogen production system is aimed at reducing the specific weight (<2 kg/kW(th) or 4 kg/kW(el)) combined with high efficiency for net electricity generation from methanol (about 50%) and low specific emissions. The application of Pd-membranes as gas cleaning unit fulfill the requirements with high hydrogen permeability and low cost of the noble metal. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:288 / 293
页数:6
相关论文
共 9 条
  • [1] AMPHLETT JC, 1996, INT J HYDROGEN ENERG, V21, P637
  • [2] FUEL CLEANUP SYSTEM - POISONING OF PALLADIUM-SILVER MEMBRANES BY GASEOUS IMPURITIES
    CHABOT, J
    LECOMTE, J
    GRUMET, C
    SANNIER, J
    [J]. FUSION TECHNOLOGY, 1988, 14 (02): : 614 - 623
  • [3] COLSMAN G, 1995, THESIS RWTH AACHEN
  • [4] Methanol steam-reforming in a catalytic fixed bed reactor
    Dusterwald, HG
    Hohlein, B
    Kraut, H
    Meusinger, J
    Peters, R
    Stimming, U
    [J]. CHEMICAL ENGINEERING & TECHNOLOGY, 1997, 20 (09) : 617 - 623
  • [5] EMONTS B, 1998, IN PRESS CATALYSIS T
  • [6] Hydrogen from methanol for fuel cells in mobile systems: Development of a compact reformer
    Hohlein, B
    Boe, M
    BogildHansen, J
    Brockerhoff, P
    Colsman, G
    Emonts, B
    Menzer, R
    Riedel, E
    [J]. JOURNAL OF POWER SOURCES, 1996, 61 (1-2) : 143 - 147
  • [7] HOHLEIN B, 1994, P 10 WORLD HYDR EN C, V2, P1461
  • [8] HOHLEIN B, 1996, MONOGRAPHIEN FORSCHU, V26
  • [9] RIEDEL E, 1996, THESIS RWTH AACHEN