Hydrogen peroxide, water oxide and catalysis

被引：45

作者：

Moiseev, II ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 11707, Russia

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 127卷 / 1-3期

基金：

俄罗斯基础研究基金会;

关键词：

hydrogen peroxide; organic hydroperoxides; water oxide; metal complex catalysis; alkene epoxidation; oxidation of molecules containing n-donor atoms;

D O I：

10.1016/S1381-1169(98)80128-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Data related to an oxygen atom transfer from hydrogen peroxide or organyl hydroperoxide to unsaturated and saturated hydrocarbons, trisubstituted phosphines, arsines or stibines catalyzed with metal complexes are discussed. A peroxo metal complex with the non-symmetrically coordinated peroxo ligand resembling the anion of water oxide, H2O+-O-, is suggested to play the role of transition state fragment of active species in the reactions mentioned. (C) 1997 Elsevier Science B.V.

引用

页码：1 / 23

页数：23

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