Colloidal glass transition observed in confinement

被引:130
作者
Nugent, Carolyn R. [1 ]
Edmond, Kazem V. [1 ]
Patel, Hetal N. [1 ]
Weeks, Eric R. [1 ]
机构
[1] Emory Univ, Dept Phys, Atlanta, GA 30322 USA
基金
美国国家科学基金会;
关键词
D O I
10.1103/PhysRevLett.99.025702
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We study a colloidal suspension confined between two quasiparallel walls as a model system for glass transitions in confined geometries. The suspension is a mixture of two particle sizes to prevent wall-induced crystallization. We use confocal microscopy to directly observe the motion of colloidal particles. This motion is slower in confinement, thus producing glassy behavior in a sample which is a liquid in an unconfined geometry. For higher volume fraction samples (closer to the glass transition), the onset of confinement effects occurs at larger length scales.
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页数:4
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共 27 条
  • [1] Effects of confinement on material behaviour at the nanometre size scale
    Alcoutlabi, M
    McKenna, GB
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2005, 17 (15) : R461 - R524
  • [2] Relaxation in glassforming liquids and amorphous solids
    Angell, CA
    Ngai, KL
    McKenna, GB
    McMillan, PF
    Martin, SW
    [J]. JOURNAL OF APPLIED PHYSICS, 2000, 88 (06) : 3113 - 3157
  • [3] ARCHER AJ, PHYS REV E, V75
  • [4] Glass transition in liquids: Two versus three-dimensional confinement
    Barut, G
    Pissis, P
    Pelster, R
    Nimtz, G
    [J]. PHYSICAL REVIEW LETTERS, 1998, 80 (16) : 3543 - 3546
  • [5] Three-dimensional confocal microscopy of colloids
    Dinsmore, AD
    Weeks, ER
    Prasad, V
    Levitt, AC
    Weitz, DA
    [J]. APPLIED OPTICS, 2001, 40 (24) : 4152 - 4159
  • [6] Hydrodynamic coupling of two Brownian spheres to a planar surface
    Dufresne, ER
    Squires, TM
    Brenner, MP
    Grier, DG
    [J]. PHYSICAL REVIEW LETTERS, 2000, 85 (15) : 3317 - 3320
  • [7] Spatially heterogeneous dynamics in supercooled liquids
    Ediger, MD
    [J]. ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2000, 51 : 99 - 128
  • [8] α-relaxation processes in binary hard-sphere mixtures -: art. no. 011505
    Foffi, G
    Götze, W
    Sciortino, F
    Tartaglia, P
    Voigtmann, T
    [J]. PHYSICAL REVIEW E, 2004, 69 (01): : 17
  • [9] Soft matter in a tight spot
    Granick, S
    [J]. PHYSICS TODAY, 1999, 52 (07) : 26 - 31
  • [10] Effect of particle size distribution on crystallisation and the glass transition of hard sphere colloids
    Henderson, SI
    Mortensen, TC
    Underwood, SM
    vanMegen, W
    [J]. PHYSICA A, 1996, 233 (1-2): : 102 - 116