Reversible five-component assembly of a [2]catenane from a chiral metallomacrocycle and a dinaphtho-crown ether

被引：88

作者：

Try, AC

Harding, MM ^{[1
]}

Hamilton, DG

Sanders, JKM

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[2] Univ Cambridge, Cambridge Ctr Mol Recognit, Chem Lab, Cambridge CB2 1EW, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 06期

关键词：

D O I：

10.1039/a709112e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of a dinaphtho-crown ether to the components of a chiral metallomacrocycle affords a [2]catenane as the exclusive thermodynamic product; the reversible assembly process is driven by a combination of zinc(II)-bipyridyl ligation and pi-donor/pi-acceptor interactions between the electronically complementary aromatic components.

引用

收藏

页码：723 / 724

页数：2

相关论文

共 21 条

[1] Interlocked and intertwined structures and superstructures [J].

Amabilino, DB ;

Stoddart, JF .

CHEMICAL REVIEWS, 1995, 95 (08) :2725-2828

[2] Cyclobis(paraquat-4,4'-biphenylene) - An organic molecular square [J].

Asakawa, M ;

Ashton, PR ;

Menzer, S ;

Raymo, FM ;

Stoddart, JF ;

White, AJP ;

Williams, DJ .

CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (07) :877-893

[3] GUEST-INDUCED ASSEMBLY OF A CHIRAL [2+2] METALLOMACROCYCLE [J].

BILYK, A ;

HARDING, MM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) :1697-1698

[4] Selection approaches to catalytic systems [J].

Brady, PA ;

Sanders, JKM .

CHEMICAL SOCIETY REVIEWS, 1997, 26 (05) :327-336

[5] Templating and clipping coordination reactions leading to heteronuclear trimetallic complexes containing interlocking rings [J].

Cardenas, DJ ;

Sauvage, JP .

INORGANIC CHEMISTRY, 1997, 36 (13) :2777-2783

[6] TRANSITION-METALS AS ASSEMBLING AND TEMPLATING SPECIES - FROM CATENANES AND KNOTS TO STRINGS THREADED THROUGH MOLECULAR RINGS [J].

CHAMBRON, JC ;

DIETRICHBUCHECKER, CO ;

NIERENGARTEN, JF ;

SAUVAGE, JP .

PURE AND APPLIED CHEMISTRY, 1994, 66 (07) :1543-1550

[7] Supramolecular self-assembly of macrocycles, catenanes, and cages through coordination of pyridine-based ligands to transition metals [J].

Fujita, M ;

Ogura, G .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (06) :1471-1482

[8] Made-to-order assembling of [2]catenanes from palladium(II)-linked rectangular molecular boxes [J].

Fujita, M ;

Aoyagi, M ;

Ibukuro, F ;

Ogura, K ;

Yamaguchi, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (03) :611-612

[9] QUANTITATIVE SELF-ASSEMBLY OF A [2]CATENANE FROM 2 PREFORMED MOLECULAR RINGS [J].

FUJITA, M ;

IBUKURO, F ;

HAGIHARA, H ;

OGURA, K .

NATURE, 1994, 367 (6465) :720-723

[10] FORMATION OF THE 1ST ORGANOMETALLIC CATENANE [J].

GRUTER, GJM ;

DEKANTER, FJJ ;

MARKIES, PR ;

NOMOTO, T ;

AKKERMAN, OS ;

BICKELHAUPT, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (25) :12179-12180