Polymeric monolithic materials: Syntheses, properties, functionalization and applications

被引：231

作者：

Buchmeiser, Michael R.

机构：

[1] Leibniz Inst Oberflachenmodifizierung eV, D-04318 Leipzig, Germany

[2] Univ Leipzig, Inst Chem Tech, D-04103 Leipzig, Germany

来源：

POLYMER | 2007年 / 48卷 / 08期

关键词：

monolithic materials; polymer materials; polymer synthesis;

D O I：

10.1016/j.polymer.2007.02.045

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthetic particularities for the synthesis of polymer-based monolithic materials are summarized. In this context, monoliths prepared via thermal-, UV- or electron-beam triggered free radical polymerization, controlled TEMPO-mediated radical polymerization, polyaddition, polycondensation as well as living ring-opening metathesis polymerization (ROMP) will be covered. Particular attention is devoted to the aspects of controlling pore sizes, pore volumes and pore size distributions as well as functionalization of these supports. Finally, selected, recent applications in separation science, (bio-) catalysis and chip technology will be summarized. (c) 2007 Elsevier Ltd. All rights reserved.

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页码：2187 / 2198

页数：12

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